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Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of supportand metal nanoparticle size on catalyst activity and products selectivity

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 2,   Pages 299-309 doi: 10.1007/s11705-020-1925-x

Abstract: In this paper, a series of cobalt catalysts supported on reduced graphene oxide (rGO) nanosheets withThe results showed that with increasing the cobalt loading on the rGO support, the carbon defects areincreased and as a consequence, the reduction of cobalt is decreased.The FTS activity results showed that the cobalt-time yield and turnover frequency passed from a maximumfor catalyst with the Co average particle size of 15 nm due to the synergetic effect of cobalt reducibility

Keywords： cobalt catalyst     cobalt particle size     Fischer-Tropsch synthesis     reduced graphene oxide     supported catalyst    

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Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 3,   Pages 262-269 doi: 10.1007/s11705-013-1334-5

Abstract: The addition of Au as a promoter/modifier for alumina supported Co catalyst has been studied by combinedThe combination of these tools permitted the state of the active catalyst surface to be monitored whilefollowing the elution of reaction products during the first 5–7 h on stream of the catalyst.During the initial stages of reaction, hydrocarbons were built up on the surface of the catalyst as monitoredpresence of Au while the later also shifted the CO/H balance by acting as an effective water-gas shift catalyst

Keywords： gold modified catalyst     conversion of synthesis gas    

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Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 1,   Pages 45-51 doi: 10.1007/s11705-009-0308-0

Abstract: Both cubic and spherical CoPt nanoparticles were made using cobalt carbonyl and platinum 2,4-pentanedionateEffects of heterogeneous species on shape of the CoPt nanoparticles were examined by replacing cobaltthat the formation of different shapes of CoPt particles could be attributed to the affinity between cobalt

Keywords： spherical     2     4-pentanedionate     adamantanecarboxylic     acetylacetonate     electrocatalytic    

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Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1550-1560 doi: 10.1007/s11705-021-2104-4

Abstract: In this work, cobalt nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysisof a cobalt covalent organic framework under an inert atmosphere.compared to N-doped carbon without the addition of Co nanoparticles, indicating the important role of cobaltstrong methanol tolerance and superior durability, these results are comparable to those of the Pt/C catalyst

Keywords： cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1440-1449 doi: 10.1007/s11705-023-2333-9

Abstract: was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobaltThe effects of in-situ doping of the cobalt element on the micromorphology and electrochemicalAfter in-situ doping of the cobalt element, NiS with a needle-like structure was converted intoThis result indicated that the in-situ doping of the cobalt element promoted the electrochemical

Keywords： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 6,   Pages 945-951 doi: 10.1007/s11783-013-0615-z

Abstract: A potentiometric cobalt-based screen-printing sensor was fabricated by electroplating cobalt on the surfaceThe cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10

Keywords： phosphate     cobalt     screen-printing technology     electroplate     wastewater    

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Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Mehraneh Ghavami, Mostafa Aghbolaghy, Jafar Soltan, Ning Chen

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 937-947 doi: 10.1007/s11705-019-1900-6

Abstract: In this study, a series of alumina supported single and mixed manganese and cobalt oxides catalysts wereaugmenting the single Mn and Co catalysts were investigated on the performance and structure of the catalystThe manganese and cobalt single and mixed oxides catalysts of the formula Mn10%-CoX and Co10%-MnX (where

Keywords： ozone     VOC     manganese oxides     cobalt oxides     alumina support    

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Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 948-955 doi: 10.1007/s11705-020-1920-2

Abstract: Cobalt hydroxide has been emerging as a promising catalyst for the electrocatalytic oxidation reactionsHerein, we prepared cobalt hydroxide nanoparticles (CoHP) and cobalt hydroxide nanosheets (CoHS) on nickel

Keywords： electrocatalytic oxidation     cobalt hydroxide     nanosheet     water     glucose    

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Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 9,   Pages 1367-1376 doi: 10.1007/s11705-022-2153-3

Abstract: Transition metal phosphides are emerging as promising catalyst candidates because of their superb activityHerein, a novel metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrid was developedby a carbothermal reduction of cobalt/nickel phosphonate hybrids with different Co/Ni molar ratios.

Keywords： metal phosphonate     cobalt/nickel phosphide     N-doped carbon     oxygen electrochemistry     Zn−air battery    

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Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layered

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1593-1607 doi: 10.1007/s11705-023-2348-2

Abstract: utilized as a substrate to integrate highly conductive polypyrrole and active nanoflower-like nickel-cobalt

Keywords： cellulose nanofibril     aerogel     nickel-cobalt layered double hydroxide     polypyrrole     nonenzymatic glucose    

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Experimental studies on extraction of cobalt ions from dilute aqueous solutions by using complexation-ultrafiltration

Jianxian ZENG, Junfeng LIU, Niandong HUANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 360-366 doi: 10.1007/s11705-009-0269-3

Abstract: The extraction of cobalt ions from dilute aqueous solutions was investigated by ultrafiltration withindicated that loading ratio, pH value and low-molecular competitive complexing agent affect significantly cobaltThe decomplexation ratio of cobalt-PAASS complex reaches as high as 90.1%.Cobalt ions can be extracted satisfactorily from the retentate, and a purified PAASS is obtained.
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Synthesis of cobalt vanadium nanomaterials for efficient electrocatalysis of oxygen evolution

Meifeng Hao, Mingshu Xiao, Lihong Qian, Yuqing Miao

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 409-416 doi: 10.1007/s11705-017-1689-0

Abstract:

A low-cost and high-activity catalyst for oxygen evolution reaction (OER) is the key to the water

Keywords： Co3(VO4)2     oxygen evolution reaction     electrocatalyst     water splitting    

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Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1487-1499 doi: 10.1007/s11705-021-2085-3

Abstract: Developing cost-effective electrocatalysts for oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is vital in energy conversion and storage applications. Herein, we report a simple method for the synthesis of graphene-reinforced CoS/C nanocomposites and the evaluation of their electrocatalytic performance for typical electrocatalytic reactions. Nanocomposites of CoS embedded in N, S co-doped porous carbon and graphene (CoS@C/Graphene) were generated via simultaneous sulfurization and carbonization of one-pot synthesized graphite oxide-ZIF-67 precursors. The obtained CoS@C/Graphene nanocomposites were characterized by X-ray diffraction, Raman spectroscopy, thermogravimetric analysis-mass spectroscopy, scanning electronic microscopy, transmission electronic microscopy, X-ray photoelectron spectroscopy and gas sorption. It is found that CoS nanoparticles homogenously dispersed in the in situ formed N, S co-doped porous carbon/graphene matrix. The CoS@C/10Graphene composite not only shows excellent electrocatalytic activity toward ORR with high onset potential of 0.89 V, four-electron pathway and superior durability of maintaining 98% of current after continuously running for around 5 h, but also exhibits good performance for OER and HER, due to the improved electrical conductivity, increased catalytic active sites and connectivity between the electrocatalytic active CoS and the carbon matrix. This work offers a new approach for the development of novel multifunctional nanocomposites for the next generation of energy conversion and storage applications.

Keywords： MOF derivative     graphene     electrocatalyst     oxygen reduction reaction     oxygen evolution reaction     hydrogen evolution reaction    

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Effects of ancillary ligands in acceptorless benzyl alcohol dehydrogenation mediated by phosphine-free cobalt

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 3,   Pages 314-325 doi: 10.1007/s11705-022-2219-2

Abstract: The catalyst showed excellent performance with a turnover number of 130.4 and a selectivity close to

Keywords： acceptorless alcohol dehydrogenation     η5-C5Me5-Co     metal–ligand cooperation     theoretical calculation    

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Modeling nanostructured catalyst layer in PEMFC and catalyst utilization

Jiejing ZHANG, Pengzhen CAO, Li XU, Yuxin WANG

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 297-302 doi: 10.1007/s11705-011-1201-1

Abstract: A lattice model of the nanoscaled catalyst layer structure in proton exchange membrane fuel cells (PEMFCThe model takes into account all the four components in a typical PEMFC catalyst layer: platinum (Pt)elemental voxels in the lattice were set fine enough so that each average sized Pt particulate in Pt/C catalystCatalyst utilization in the modeled catalyst layer was calculated by counting up the number of facets, on catalyst utilization were investigated and discussed.

Keywords： catalyst layer     PEM fuel cell     lattice model     Monte Carlo method     catalyst utilization    

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Title Author Date Type Operation

Fischer-Tropsch synthesis by reduced graphene oxide nanosheets supported cobalt catalysts: Role of supportand metal nanoparticle size on catalyst activity and products selectivity

Hasan Oliaei Torshizi, Ali Nakhaei Pour, Ali Mohammadi, Yahya Zamani, Seyed Mehdi Kamali Shahri

Journal Article

Gold modified cobalt-based Fischer-Tropsch catalysts for conversion of synthesis gas to liquid fuels

Alan J. McCue, Jura Aponaviciute, Richard P.K. Wells, James A. Anderson

Journal Article

Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Journal Article

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

Journal Article

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Journal Article

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

Journal Article

Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Mehraneh Ghavami, Mostafa Aghbolaghy, Jafar Soltan, Ning Chen

Journal Article

Noble-metal-free cobalt hydroxide nanosheets for efficient electrocatalytic oxidation

Jie Lan, Daizong Qi, Jie Song, Peng Liu, Yi Liu, Yun-Xiang Pan

Journal Article

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen

Journal Article

Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layered

Journal Article

Experimental studies on extraction of cobalt ions from dilute aqueous solutions by using complexation-ultrafiltration

Jianxian ZENG, Junfeng LIU, Niandong HUANG,

Journal Article

Synthesis of cobalt vanadium nanomaterials for efficient electrocatalysis of oxygen evolution

Meifeng Hao, Mingshu Xiao, Lihong Qian, Yuqing Miao

Journal Article

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient

Journal Article

Effects of ancillary ligands in acceptorless benzyl alcohol dehydrogenation mediated by phosphine-free cobalt

Journal Article

Modeling nanostructured catalyst layer in PEMFC and catalyst utilization

Jiejing ZHANG, Pengzhen CAO, Li XU, Yuxin WANG

Journal Article